Assuming this data is on Sheet1:
1) On Sheet2 used Edit |Fill ->Series to get numbers 1 to 500 in A1:A500
2) On Sheet2 in B1 enter =IF(COUNTIF(Sheet1!C:C,Sheet2!A1)=0,"Free","")
3) Copy this down to B500 - double click the fill handle (solid square in
lower right corner of active cell)
Now you know the free numbers
4) On Sheet2 in C1 enter =IF(COUNTIF(Sheet1!C:C,Sheet2!A1)>1,"Multiple","")
and copy down to C500
Now you know the multiple numbers
Alternative formula
=IF(COUNTIF(Sheet1!C:C,Sheet2!A1)=0,A1,"")
=IF(COUNTIF(Sheet1!C:C,Sheet2!A1)>1,A1,"")
will list the free and multiple numbers in separate columns
best wishes

Signature
Bernard V Liengme
www.stfx.ca/people/bliengme
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> Hi all
> A colleague of mine has to sort out library numbers of children at our
[quoted text clipped - 10 lines]
> The data is very simple stored as:
> pupil first name, pupil surname, library number.