Almost.
An easier way is to first show a Table-based view - add the Advanced Toolbar
if it isn't enabled and choose "All Appointments" form the drop-down list
will do.
Right-click on the field headers and choose Fields Chooser.
Click New to create a new field.
Name it - say, "Have Printed".
Choose its type and Format. Say, "Yes/No" with Format "Yes/No"
Click OK and it's added to your fields.
then drag it to where you want it in the list of fields at the top of the
view.
Close the field chooser.

That's a start if you haven't used it before. You can create a different
field type or add fields to the view or whatever.

There's a actually a "Printed" field in "All Documents Fields" but I'm not
sure how it works.