This may be either incompatible add-ins or the printer driver. See this FAQ
for help diagnosis: http://word.mvps.org/FAQs/AppErrors/ProbsOpeningWord.htm

Signature
Terry Farrell - MS Word MVP
> Why does Word 2007 stop responding when I try to save, print or exit? I've
> run diagnostics without success. I've even uninstalled and reinstalled
> Office
> 2007 to no avail. This does not happen with any other Office 2007 program
> (e.g. PowerPoint).