You can add a direct link to the Envelopes and Labels dialog to any toolbar.
See http://word.mvps.org/FAQs/Customization/AsgnCmdOrMacroToToolbar.htm. The
command you want is Envelopes and Labels... in the Tools category. It has an
envelope icon.
You can also add direct access to the New dialog. You want the FileNewDialog
command in All Commands. You'll have to change the name from Other... and
add an icon (I use the one from the New button).

Signature
Suzanne S. Barnhill
Microsoft MVP (Word)
Words into Type
Fairhope, Alabama USA
Word MVP FAQ site: http://word.mvps.org
Email cannot be acknowledged; please post all follow-ups to the newsgroup so
all may benefit.
> I wonder if there is a way to get, when I open Word, to pick from a list of
> templates, or a blank word document. I frequently use the mailing label and
> envelope wizard, and it is several clicks to get where I need to be.